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#1 stephanieyoong

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Posted 14 May 2005 - 01:23 PM

Q- A gas of low molecular mass will diffuse through air more rapidly than gas of high molecular mass even though both are at teh same temperatures.

Is it because the density affects the speed? Like if its heavier its slower than a gas with the lighter molecular mass? i think i missed this sess of chem sad.gif

#2 The Wedge Effect

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Posted 14 May 2005 - 02:15 PM

QUOTE(stephanieyoong @ May 14 2005, 02:23 PM)
Q- A gas of low molecular mass will diffuse through air more rapidly than gas of high molecular mass even though both are at teh same temperatures.

Is it because the density affects the speed? Like if its heavier its slower than a gas with the lighter molecular mass? i think i missed this sess of chem  sad.gif

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Mmm...I reckon it has to do with the covalent radius as well as the density. You see, when electron shells are added as you go down a period, the atoms overall are larger. This probably affects the rate of diffusion. I don't think I'm right, but who knows? tongue.gif

#3 Discogirl17

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Posted 14 May 2005 - 02:17 PM

Who knows? Not me anyway. I want even taught that! Must have changed the course since last year!
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#4 Dave

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Posted 14 May 2005 - 02:23 PM

she aint doing higher she is doing whatever they do in Aussie

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#5 Discogirl17

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Posted 14 May 2005 - 03:16 PM

Thats A-levels I think!
So we were never taught that then, thank god
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#6 dfx

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Posted 14 May 2005 - 03:45 PM

Her point about density does seem to make perfect logical sense though.

#7 Equilibrium

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Posted 14 May 2005 - 04:10 PM

Lower the mass means faster the speed because the molecules are lighter and smaller so they are less likely to collide with the other gas molecules. Just as electrons can travel through air more easlily than helium nuclei.
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#8 stephanieyoong

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Posted 15 May 2005 - 02:56 AM

>< hmm i tried lookin in mt text but ti doesnt acctually say anything bout the molecular mass n stuff ><

#9 werlop

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Posted 15 May 2005 - 08:55 AM

I looked at my textbook for AH chemistry and there is a big section on this I'll type up some notes later today.

I think you are interested in Graham's Law of gaseous diffusion and effusion?
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#10 stephanieyoong

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Posted 15 May 2005 - 08:57 AM

mayb, i jus need to relate the ansa to the kinetic theory but i cant see a connection. is it something to do wif the collisions?

#11 stephanieyoong

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Posted 15 May 2005 - 09:05 AM

i checked out that guy's gas law but it doesnt say anything about molecular mass n such.. here the link if u want it

http://www.scientia.org/cadonline/Chemistr...netictheory.ASP

its at the bottom. but i dont get how this law relates to the kinetic theory...

#12 werlop

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Posted 15 May 2005 - 09:17 AM

Basically density and mass both affect speed.

The rate can be considered as a measure of the speed:

Relationship between rate and density:

user posted image

Relationship between mass and density:

user posted image

Where M is the molar mass.

Remember that user posted image

M - Molar mass, V - molar volume
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Or being hated, don't give way to hating,
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#13 stephanieyoong

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Posted 15 May 2005 - 09:19 AM

but how does the kinetic theory come into all of this :S im all muddled up ><

#14 Ally

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Posted 15 May 2005 - 07:23 PM

Hmmm... I found this, maybe it'll help you.

kinetic theory of gases: an explanation of why gases obey the gas laws. The theory is based on a model of an ideal gas. The assumptions are that:
  • a gas consists of molecules in rapid, random motion.
  • the volume of the molecules can be neglected in comparison with the total volume of gas
  • the molecules do not attract each other (no intermolecular forces)
  • the collisions with the walls of any container are perfectly elastic.

By applying Newton's laws of motion and then assuming that the average kinetic energy of molecules is proportional to temperature, it is possible to derive the ideal gas equation from this model.

The model helps to explain why real gases deviate from ideal gas behaviour.

The model of gas molecules in rapid random motion underlies the theories of reaction kinetics and chemical equilibrium.

#15 Equilibrium

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Posted 15 May 2005 - 07:40 PM

happy.gif smaller the molecule, the less likely its molecules will collide with air molecules so it will diffuse through the air faster.
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#16 Moral Fabric

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Posted 18 May 2005 - 06:41 PM

QUOTE(Dave @ May 14 2005, 03:23 PM)
she aint doing higher she is doing whatever they do in Aussie

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why she on a Higher Still Notes website then huh.gif

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Posted 18 May 2005 - 06:49 PM

Stop spamming please, see that warn level bar, I can put that up you know
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#18 werlop

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Posted 19 May 2005 - 09:31 AM

QUOTE(Discogirl17 @ May 18 2005, 07:49 PM)
Stop spamming please, see that warn level bar, I can put that up you know

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Sorry, who is spamming?
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If you can keep your head when all about you
Are losing theirs and blaming it on you,
If you can trust yourself when all men doubt you
But make allowance for their doubting too,
If you can wait and not be tired by waiting,
Or being lied about, don't deal in lies,
Or being hated, don't give way to hating,
And yet don't look too good, nor talk too wise:
Yours is the Earth and everything that's in it,
And--which is more--you'll be a Man, my son!

#19 Discogirl17

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Posted 19 May 2005 - 01:55 PM

Moral Fabric, but its ok he's stopped now. It wasnt on this thread, just in general
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#20 stephanieyoong

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Posted 22 May 2005 - 07:03 AM

hehe thanx guys! ^^ i think i got it now ^^ cheers all





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